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Lecture 1 Thermodynamics of Surfaces; Equilibrium

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The First Law of Thermodynamics The first law of thermodynamics is an expression of the conservation of energy principle Energy can cross the boundaries of a closed system in the form of heat or work Energy transfer across a system boundary due solely to the temperature difference between a system and its surroundings is called heatThermodynamics the study of the transformations of energy from one form into another First Law: Heat and Work are both forms of Energy in any process, Energy can be changed from one form to another (including heat and work), but it is never created or distroyed: Conservation of Energy Thermodynamics Texas A&M University

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influential 1923 textbook Thermodynamics and the Free Energy of Chemical Reactions by Gilbert N Lewis and Merle Randall led to the replacement of the term “affinity” by the term “free energy” in much of the Englishspeaking world Graphical interpretation Gibbs free energyThis session is the second of three lectures on thermodynamics and focuses on Gibbs free energy and entropy Lecture 16: Thermodynamics: Gibbs Free Energy and

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